Layering With Leather(ette)

It's funny how something you've been searching for can be right under your nose, I've been looking for leather (and vegan leather) pants for quite some time now and I've had to return numerous pairs because they just don't seem to fit. Finally I took a tip from a girlfriend and dropped into Target and tried on a pair of their faux leather pants and immediately fell in love, my only complaint is that they stretch after wearing for a couple hours, but I'm sure they'll go back after washing. 

How perfect are they with this skull scarf and blazer?
scarf happyscarf.com (here), tee old navy, pants target, bag vintage, shoes vince camuto, blazer sheinside